The main types of glass are:
>Commercial Glass (also
known as Soda-lime glass)
> Lead Glass
> Borosilicate Glass
> Glass Fibre
Glasses may be devised to meet almost any
imaginable requirement. For many specialised applications
in chemistry, pharmacy, the electrical and electronics
industries, optics, the construction and lighting industries,
glass, or the comparatively new family of materials known
as glass ceramics, may be the only practical material
for the engineer to use.
Types of special glass include:
> Vitreous silica
> Aluminosilicate glass
> Alkali-barium silicate glass
> Technical Glass
> Glass Ceramics
> Optical glass
> Sealing glass
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Most of the glass we see around us
in our everyday lives in the form of bottles and
jars, flat glass for windows or for drinking glasses
is known as commercial glass or soda-lime glass,
as soda ash is used in its manufacture.
The main
constituent of practically all commercial glass
is sand. Sand by itself can be fused to produce
glass but the temperature at which this can be achieved
is about 1700oC. Adding other chemicals to sand
can considerably reduce the temperature of fusion.
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The addition of sodium carbonate (Na2CO3),
known as soda ash, in a quantity to produce a fused mixture
of 75% silica (SiO2) and 25% of sodium oxide (Na2O), will
reduce the temperature of fusion to about 800oC. However,
a glass of this composition is water-soluble and is known
as water glass. In order to give the glass stability,
other chemicals like calcium oxide (CaO) and magnesium
oxide (MgO) are needed.
Commercial glass is normally colourless,
allowing it to freely transmit light, which is what makes
glass ideal for windows and many other uses. Additional
chemicals have to be added to produce different colours
of glass such as green, blue or brown glass.
Most commercial glasses have roughly similar
chemical compositions of:
70% - 74% SiO2 (silica)
12% - 16% Na2O (sodium oxide)
5% - 11% CaO (calcium oxide)
1% - 3% MgO (magnesium oxide)
1% - 3% Al2O3 (aluminium oxide)
Flat glass is similar in composition to
container glass except that it contains a higher proportion
of magnesium oxide.
Within these limits the composition is varied
to suit a particular product and production method. The
raw materials are carefully weighed and thoroughly mixed,
as consistency of composition is of utmost importance
in making glass.
Nowadays recycled glass from bottle banks,
known as cullet, is used to make new glass. Using cullet
has many environmental benefits, it preserves the countryside
by reducing quarrying, and because cullet melts more easily,
it saves energy and reduces emissions.
Almost any proportion of cullet can be added
to the mix (known as batch), provided it is in the right
condition, and green glass made from batch containing
95% of cullet is now common.
Although the glass collected through bottle
banks may come from manufacturers around the world, it
can be used by one of them, as container glass compositions
are very similar. It is, however, important that glass
colours are not mixed and that the cullet is free from
impurities, especially metals and ceramics.
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Commonly known as lead crystal, lead
glass is used to make a wide variety of decorative
glass objects.
It is made by using lead oxide instead
of calcium oxide, and potassium oxide instead of
all or most of the sodium oxide. The traditional
English full lead crystal contains at least 30%
lead oxide (PbO) but any glass containing at least
24% PbO can be described as lead crystal. Glass
containing less than 24% PbO, is known simply as
crystal glass. The lead is locked into the crystal
structure of the glass so there is no risk to human
health.
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Lead glass has a high refractive index meaning
it sparkles and a relatively soft surface so that it is
easy to decorate by grinding, cutting, engraving which
highlights the crystal's brilliance making it popular
for glasses, decanters and other decorative objects.
However, glass with even higher lead oxide
contents (typically 65%) may be used as radiation shielding
because of the well-known ability of lead to absorb gamma
rays and other forms of harmful radiation.
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Most of us are more familiar with
this type of glass in the form of ovenware and other
heat-resisting ware, better known under the trade
name Pyrex.
Borosilicate glass, the third major
group, is made mainly of silica (70-80%) and boric
oxide (7-13%) with smaller amounts of the alkalis
(sodium and potassium oxides) and aluminium oxide.
This type of glass has a relatively low alkali content
and consequently has good chemical durability and
thermal shock resistance (it doesn't break when
changing temperature quickly). As a result it is
widely used in the chemical industry, for laboratory
apparatus, for ampoules and other pharmaceutical
containers, for various high intensity lighting
applications and as glass fibres for textile and
plastic reinforcement.
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Glass fibre has many uses from roof
insulation to medical equipment and its composition
varies depending on its application.
For building insulation and glass
wool the type of glass used is normally soda lime.
For textiles, an alumino-borosilicate glass with
very low sodium oxide content is preferred because
of its good chemical durability and high softening
point. This is also the type of glass fibre used
in the reinforced plastics to make protective helmets,
boats, piping, car chassis, ropes, car exhausts
and many other items.
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In recent years, great progress has been
made in making optical fibres which can guide light and
thus transmit images round corners. These fibres are used
in endoscopes for examination of internal human organs,
changeable traffic message signs now on motorways for
speed restriction warnings and communications technology
without which telephones and the internet would not be
possible
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Silica glass or vitreous silica is
of considerable technical importance as it has a
very low thermal expansion. This difficult to make
glass contains tiny holes created using acids and
is used for filtration. Porous glasses of this kind
are commonly known as Vycor.
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A small, but important type of glass,
aluminosilicate, contains 20% aluminium oxide (alumina-Al2O3)
often including calcium oxide, magnesium oxide and
boric oxide in relatively small amounts, but with
only very small amounts of soda or potash. It is
able to withstand high temperatures and thermal
shock and is typically used in combustion tubes,
gauge glasses for high-pressure steam boilers, and
in halogen-tungsten lamps capable of operating at
temperature as high as 750oC.
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| Alkali-barium
Silicate Glass |
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Without this type of glass watching
TV would be very dangerous. A television produces
X-rays that need to be absorbed, otherwise they
could in the long run cause health problems. The
X-rays are absorbed by glass with minimum amounts
of heavy oxides (lead, barium or strontium). Lead
glass is commonly used for the funnel and neck of
the TV tube, while glass containing barium is usually
used for the screen.
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Without borate glass the computer
revolution would not have been possible as it's
vitally important in producing electrical components.
This type of glass, contains little or no silica
and is used for soldering glass, metals or ceramics
as it melts at the relatively low temperature of
450-550oC, well below that of normal glass, ceramics
and many metals.
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Glass of a slightly different composition
is used for protecting silicon semi-conductor components
against chemical attack and mechanical damage. Known as
passivation glass it is vital in microelectronics technology
and the production of the silicon chips inside computers.
Another type of glass - Phosphate Glass
- which is a semi conductor, is used in the construction
of secondary electron multipliers.
Chalcogenide glass - Similar semi conductor
effects are also characteristic of a type of glass that
can be made without the presence of oxygen. Some of them
have potential use as infrared transmitting materials
and as switching devices in computer memories because
their conductivity changes abruptly when particular threshold
voltage values are exceeded
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Some of these "Glass ceramics",
formed typically from lithium aluminosilicate glass,
are extremely resistant to thermal stock and have
found several applications where this property is
important, including cooker hobs, cooking ware,
windows for gas or coal fires, mirror substrates
for astronomical telescopes and missile nose cones.
An essential feature of glass is that
it does not contain crystals. However, by deliberately
stimulating crystal growth in glass it is possible
to produce a type of glass with a controlled amount
of crystallisation that can combine many of the
best features of ceramics and glass.
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Optical glasses will be found in scientific
instruments, microscopes, fighter aircraft and most
commonly in spectacles.
The most important properties are
the refractive index and the dispersion. The index
is a measure of how much the glass bends light.
The dispersion is a measure of the way the glass
splits white light into the colours of the rainbow.
Glass makers use the variations in these characteristics
to develop optical glasses.
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Another application for which a large
variety of glass compositions is used is sealing
to metals for electrical and electronic components.
Here the available glasses may be grouped according
to their thermal expansion which must be matched
with the thermal expansions of the respective metals
so that sealing is possible without excessive strain
being induced by the expansion differences.
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For sealing to tungsten, in making incandescent
and discharge lamps, borosilicate alkaline earths-aluminous
silicate glasses are suitable. Sodium borosilicate glasses
may be used for sealing to molybdenum and the iron-nickel-cobalt
(Fernico) alloys are frequently employed as a substitute,
the amount of sodium oxide permissible depending on the
degree of electrical resistance required. With glasses
designed to seal to Kovar alloy, relatively high contents
of boric oxide (approximately 20%) are needed to keep
the transformation temperature low and usually the preferred
alkali is potassium oxide so as to ensure high electrical
insulation.
Where the requirement for electrical insulation
is paramount, as in many types of vacuum tube and for
the encapsulation of diodes, a variety of lead glasses
(typical containing between 30% and 60% lead oxide) can
be used.